Perspectives on Chemical Modification of Carbon Nanomaterials Assisted by Microwave Radiation - Crimson Publishers
Perspectives on Chemical Modification of Carbon Nanomaterials Assisted by Microwave Radiation by Hélio Ribeiro* in Crimson Publishers: Peer Reviewed Material Science Journals
Carbon nanomaterials (CNMs) as
graphene and carbon nanotubes (CNTs) have attracted attention of scientific
community due to their high performance and applications. However, their
potential applications as nanofillers, depends necessarily of their production
which high structural quality, great compatibility with the host system. For
instance, in polymeric matrices this issue involves several challenges due to
their low dispersibility in water and organic solvents, thus different process
of chemical modification of CNMs surfaces have been reported. In cases of
functionalization with amino groups, most of them use in one of their chemical
steps thionyl chloride (SOCl2) as intermediate reagent. In general, the use of
SOCl2 limits the chemical process, due to of its dangerous nature and high
level of toxicity. Another drawback found in this kind of methodology is the
time spent on reflux lasting days and making it a very onerous process. In this
context, the chemical modification of CNMs assisted by microwave radiation has
been explored in synthesis, purification and chemical modification processes of
these nanostructures resulting in simpler and faster procedures that allow its
used on a large scale and with low environmental impact.
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